Rose Group Publications (MJR Independent Career)
(see Research sub-topics for TOC graphics)
62. T. Ho, B. J. Lee, T. Buchanan, M. Heikes, R. Steinert, E. Milem, S. T. Goralski, Y.-N. Wang, S.-H. Lee, V. M. Lynch, M. J. Rose, K. Mitchell-Koch, K. Hull*. Mechanistic Investigation into the Copper-Catalyzed Three-Component Carboamination of Alkenes. In Revisions.
61. C. R. Cobb, R. K. Ngo, E. Dick, V. M. Lynch and M. J. Rose*. Multi-Phosphine-Chelated Iron-Carbide Clusters via Redox–Promoted Ligand Exchange on an Inert Hexa-Iron-Carbide Carbonyl Cluster, [Fe6(μ6-C)(μ2-CO)4(CO)12]2–. In Revisions.
60. C. D. Hallock and M. J. Rose*. Electrochemical Impedance of Well-Passivated Semiconductors Reveals Bandgaps, Fermi Levels and Interfacial Density of States. In Revisions.
59. A. T. Larson, B. Boyle, J. Labrecque, A. Ly, C. Bui, S. Vasylevskyi and M. J. Rose*. Synthesis & Conformational Dynamics of Selenanthrene (Oxides): Establishing an ‘Energetic Flexibility Index’ for Scaffolds. Inorg. Chem. 2024, Accepted!
58. M. J. Rose*. Semiconductor Band Structure, Symmetry & Interface Hybridization for the Chemist.
J. Am. Chem. Soc. 2024, 146, 5735-5748
DOI: 10.1021/jacs.3c07740
**JACS Perspective article on the Symmetry & Group Theory of Silicon|Molecule Interfaces!**
57. J. M. Strain#, G. N. Ruiz#, S. T. Roberts and M. J. Rose*. Methylation of Si(111) Modulates Molecular Orientation in Perylenediimide Thin Films.
Langmuir 2024, 40, 2519-2530
DOI: 10.1021/acs.langmuir.3c02569
56. J. Labrecque, Y. I. Cho, D. K. McIntosh, F. Agboola and M. J. Rose*. Distal Scaffold Flexibility Accelerates Ligand Substitution Kinetics in Manganese(I) Tricarbonyls: Flexible Thianthrene versus Rigid Anthracene.
Dalton Trans. 2023, 52, 4028-4037
DOI: 10.1039/D2DT04048D
55. S. T. Goralski, K. M. Cid-Seara, J. J. Jarju, L. Rodriguez-Lorenzo, A. P. LaGrow, M. J. Rose* and L. M. Salonen*. Threefold Reactivity of a COF-Embedded Rhenium Catalyst: Reductive Etherification, Oxidative Esterification or Transfer Hydrogenation.
Chem. Commun. 2022, 12074-12077
DOI: 10.1039/D2CC03173F
54. J. M. Gurrentz, K. A. Jarvis, I. R. Gearba-Dolocan and M. J. Rose*. Atomic Layer Deposited Al2O3 as a Protective Overlayer for Focused Ion Beam Preparation of Plan-View STEM Samples.
Ultramicroscopy 2022, 239, 113562
DOI: 10.1016/j.ultramic.2022.113562
53. W. V. Taylor, B. K. Cashman, Z.-L. Xie, K. K. Ngo and M. J. Rose*. Synthesis and Magnetic Properties of Antimony-Ligated Co(II) Complexes: Stibines versus Phosphines.
Inorg. Chem. 2022, 61, 6733-6741
DOI: 10.1021/acs.inorgchem.1c03366
52. S. T. Goralski and M. J. Rose*. Emerging Artificial Metalloenzymes Asymmetric Hydrogenation Reactions.
Curr. Opin. Chem. Biol. 2021, 102096
DOI: 10.1016/j.cbpa.2021.102096
51. S. A. Kerns#, J. Seo#, V. M. Lynch, J. Shearer, S. T. Goralski, E. R. Sullivan and M. J. Rose*. Scaffold-Based [Fe]-Hydrogenase Model: H2 Activation Initiates Fe(0)-Hydride Extrusion and Non-Biomimetic Hydride Transfer.
Chem. Sci. 2021, 12, 12838-12846
DOI: 10.1039/D0SC03154B
50. J. M. Gurrentz and M. J. Rose*. Covalent Attachment of Polyoxometalates to Passivated Si(111) Substrates: A Stable and Electronic Defect-Free Si|POM Platform.
J. Phys. Chem. C. 2021, 125, 14287-14298
DOI: 10.1021/acs.jpcc.1c04015
49. D. G. Boucher, K. L. Kearney, E. Ertekin and M. J. Rose*. Tuning p-Si(111) Photovoltage via Molecule|Semiconductor Electronic Coupling.
J. Am. Chem. Soc. 2021, 143, 2567-2580
DOI: 10.1021/jacs.0c12075
48. C. Joseph, C. R. Cobb and M. J. Rose*. Single-Step Insertion of Sulfides and Thiolate into Iron Carbide-Carbonyl Clusters: Unlocking the Synthetic Door to FeMoco Analogues.
Angew. Chem. Intl. Ed. 2021, 133, 3475-3479
DOI: 10.1002/ange.202011517
**ACIE “Hot Paper”!**
47. M. J. Rose*. [Fe]-Hydrogenase (Hmd): Insights from Enzyme Structure, Spectroscopy and Synthetic Models.
Comprehensive Coordination Chemistry III 2021
DOI: 10.1016/B978-0-12-409547-2.14852-8
46. C. Joseph, J. P. Shupp, C. R. Cobb and M. J. Rose*. Construction of Synthetic Models for Nitrogenase Relevant NifB Biogenesis Intermediates and Iron-Carbide-Sulfide Clusters.
Catalysts (Bio-Inorganic Special Edition) 2020, 10, 1317
DOI: 10.3390/catal10111317
45. S. A. Kerns and M. J. Rose*. Scaffold-based Functional Models of [Fe]-Hydrogenase: Building the Bridge between Biological Structure and Molecular Function.
Acc. Chem. Res. 2020, 53, 1637-1647
DOI: 10.1021/acs.accounts.0c00315
44. J. M. Gurrentz and M. J. Rose*. Non-Catalytic Benefits of Ni(II) Binding to an Si(111)-PNP Construct for Photoelectrochemical Hydrogen Evolution Reaction: Metal Ion Induced Flat Band Potential Modulation.
J. Am. Chem. Soc. 2020, 142, 5657-5667
DOI: 10.1021/jacs.9b12824
43. R. T. Perarek, D. G. Boucher, N. R. Neale and M. J. Rose*. Energetic Tug-of-War between Pt and Leaky TiO2: Positive and Negative Effects on the Function of Molecularly Modified p-Si(111)|TiO2|Pt Photocathodes.
ChemElectroChem 2020, 7, 1048-1056
DOI: 10.1002/celc.201901758
42. S. T. Goralski, T. A. Manes, S. E. A. Lumsden, V. M. Lynch and M. J. Rose*. Divergent Solution and Solid State Structures of Mono- and Dinuclear Nickel(II) Pyridone Complexes.
Organometallics 2020, 39, 1070-1070
DOI: 10.1021/acs.organomet.9b00799
41. Z.-L. Xie, W. Chai, S. A. Kerns, G. A. Henkelman and M. J. Rose*. Bioinspired CNP Iron(II) Pincers Relevant to [Fe]-Hydrogenase (Hmd): Effect of Dicarbonyl versus Monocarbonyl Motifs in H2 Activation and Transfer Hydrogenation.
Inorg. Chem. 2020, 59, 2548-2561
DOI: 10.1021/acs.inorgchem.9b03476
40. J. P. Shupp and M. J. Rose*. Facile Hydrogen Atom Abstraction and Sulfide Formation from a Methyl-Thiolate Capped Iron-Sulfur-Carbonyl Cluster.
Dalton Trans. 2020, 49, 23-26
DOI: 10.1039/C9DT04098F
39. B. K. Cashman, K. M. Sandmann and M. J. Rose*. Isolation and X-Ray Structure of Dialkylbismuth(III) Iodo “Nanosquare”: Breaking the Mold of Polymeric R2BiX.
Inorg. Chem. 2019, 58, 13751-13754
DOI: 10.1021/acs.inorgchem.9b01969
38. J. McGale, G. E. Cutsail III, C. Joseph, M. J. Rose and S. DeBeer*. Spectroscopy and Mossbauer Characterization of M6 and M5 Iron(Molybdenum) Carbide Clusters: High Carbide-Iron Covalency Enhances Local Iron Site Electron Density Despite Oxidation.
Inorg. Chem. 2019, 58, 12918-12932
DOI: 10.1021/acs.inorgchem.9b01870
37. Y. I. Cho, G. Durgaprasad and M. J. Rose*. CNS and CNP Iron(II) Mono-Iron Hydrogenase (Hmd) Mimics: Role of Deprotonated Methylene(acyl) and the trans-Acyl Site in H2 Heterolysis.
Inorg. Chem. 2019, 58, 12689-12699
DOI: 10.1021/acs.inorgchem.9b01530
36. W. V. Taylor, C. X. Cammack, S. A. Shubert and M. J. Rose*. Thermoluminescent Antimony-Supported Copper-Iodo Cuboids: Approaching NIR Emission via High Crystallographic Symmetry.
Inorg. Chem. 2019, 58, 16330-16345
DOI: 10.1021/acs.inorgchem.9b00229
**Invited Complementary Front Cover
**ACS Editor’s Choice 365 Selection
35. D. G. Boucher, J. R. Speller, R. Han, F. E. Osterloh and M. J. Rose*. Decoupling Effects of Surface Recombination and Barrier Height on p-Si(111) Photovoltage in Semiconductor|Liquid Junctions via Molecular Dipoles and Metal Oxides.
ACS Appl. Energy Mater. 2019, 2, 66-79
DOI: 10.1021/acsaem.8b01563
34. R. T. Pekarek, K. L. Kearney, B. M. Simon, E. Ertekin, A. Rockett and M. J. Rose*. Identifying Charge Transfer Mechanisms at Semiconductor Heterojunctions with Molecular Surface Dipoles and Multiscale Computational Modeling.
J. Am. Chem. Soc. 2018, 140, 13223-13232
DOI: 10.1021/jacs.8b05057
33. J. Imbrogno, R. C. Ferrier Jr, B. Wheatle, M. J. Rose and N. Lynd*. Decoupling Catalysis and Chain-Growth Functions of Mono(µ-alkoxo)-Di(alkylaluminums) in Epoxide Polymerization: Emergence of the N/Al Adduct Catalyst.
ACS Catalysis 2018, 8, 8796-8803
DOI: 10.1021/acscatal.8b02446
32. Z.-L. Xie, D. L. Pennington, D. G. Boucher, J. Lo and M. J. Rose*. Effects of Thiolate Ligation in Mono-Iron Hydrogenase (Hmd): Stability of the {Fe(CO)2}2+ Core with NNS Ligands.
Inorg. Chem. 2018, 57, 10028-10039
DOI: 10.1021/acs.inorgchem.8b01185
31. W. V. Taylor, Z.-L. Xie, N. I. Cool, S. A. Shubert and M. J. Rose*. Syntheses, Structures and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition.
Inorg. Chem. 2018, 57, 10364-10374
DOI: 10.1021/acs.inorgchem.8b01565
30. R. T. Pekarek, A. L. Bleier, E. R. Sullivan, E. A. Bevan, O. Ursi, T. H. Rose and M. J. Rose*. H2fromH2O: A Water-Splitting Kit with Instructional Applications in Secondary Education.
J. Lab. Chem. Ed. 2018, 6, 47-59
DOI: 10.5923/j.jlce.20180603.01
29. R. T. Pekarek, H. Celio and M. J. Rose*. Synthetic Insights into Surface Functionalization of Si(111)–R Photoelectrodes: Steric Control and Deprotection of Molecular Passivating Layers.
Langmuir 2018, 34, 6328-6337
DOI: 10.1021/acs.langmuir.7b03564
28. C. Joseph, S. Kuppuswamy, V. M. Lynch and M. J. Rose*. Fe5Mo Cluster with Iron-Carbide and Molybdenum-Carbide Bonding Motifs: Structure and Selective Alkyne Reductions.
Inorg. Chem. 2018, 57, 20-23
DOI: 10.1021/acs.inorgchem.7b02615
27. S. Kerns, A.-C. Magtaan, P. Vong and M. J. Rose*. Functional Hydride Transfer by a Thiolate-containing Model of Mono-iron Hydrogenase featuring an Anthracene Scaffold.
Angew. Chem. Int. Ed. 2018, 57, 2855-2858
DOI:
**ACIE VIP Top 5% paper**
26. T. A. Manes and M. J. Rose*. Rigid scaffolds for the design of molecular catalysts and biomimetic active sites: A case study of anthracene-based ligands for modeling mono-iron hydrogenase (Hmd).
Coord. Chem. Rev. 2017, 353, 295-308
DOI: 10.1016/j.ccr.2017.09.022
25. Z.-L. Xie, G. Durgaprasad and M. J. Rose*. Substitution Reactions of Iron(II) Carbamoyl-Thioether Complexes Related to Mono-Iron Hydrogenase.
Dalton Trans. 2017, 46, 10814-10829
DOI: 10.1039/C7DT01696D
24. D. W. Redman, M. J. Rose and K. J. Stevenson*. Electrodeposition of Amorphous Molybdenum Chalcogenides from Ionic Liquids and Their Activity for the Hydrogen Evolution Reaction.
Langmuir 2017, 33, 9354-9360
DOI: 10.1021/acs.langmuir.7b00821
23. J. P. Shupp, A. R. Rose and M. J. Rose*. Synthesis and Interconversions of Reduced, Alkali-Metal Supported Iron-Sulfur-Carbonyl Complexes.
Dalton Trans. 2017, 46, 9163-9171
DOI: 10.1039/C7DT01506B
22. J. Seo, T. E. Sotman, E. R. Sullivan, B. D. Ellis, T. Phung and M. J. Rose*. Structural and Electronic Modifications of Pyridones and Pyrones via Regioselective Bromination and Trifluoromethylation.
Tetrahedron 2017, 73, 4519-4528
DOI: 10.1016/j.tet.2017.05.082
21. S. Kuppuswamy, J. Wofford, C. Joseph, Z.-L. Xie, A. K. Ali, V. M. Lynch, P. A. Lindahl and M. J. Rose*. Structures, Interconversions and Spectroscopy of Carbonyl Clusters with an Interstitial Carbide: Localized Iron Center Reduction via Cluster Oxidation.
Inorg. Chem. 2017, 56, 5998-6012
DOI: 10.1021/acs.inorgchem.7b00741
20. J. Seo, T. A. Manes and M. J. Rose*. Structural and Functional Synthetic Model of Mono-Iron Hydrogenase Featuring an Anthracene Scaffold.
Nature Chem. 2017, 9, 552-557
DOI: 10.1038/nchem.2707
19. H. J. Kim, K. L. Kearney, L. H. Le, Z. J. Haber, A. A. Rockett and M. J. Rose*. Charge-Transfer through Ultrathin Film TiO2 on n-Si(111) Photoelectrodes: Experimental and Theoretical Investigation of Electric Field-Enhanced Transport with a Non-Aqueous Redox Couple.
J. Phys. Chem. C 2016, 120, 25697-25708
DOI: 10.1021/acs.jpcc.6b08096
18. Y. I. Cho, M. L. Ward and M. J. Rose*. Substituent Effects of N4 Schiff Base Ligands on the Formation of Fluoride-Bridged Dicobalt(II) Complexes via B–F Abstraction: Structures and Magnetism.
Dalton Trans. 2016, 45, 13466-13476
DOI: 10.1039/C6DT02104B
17. T. A. Manes and M. J. Rose*. Mono- and Di-nuclear Manganese Carbonyls Supported by 1,8-Disubstituted (L = Py, Ar-SMe, Ar-SH) Anthracene Ligand Scaffolds.
Inorg. Chem. 2016, 55, 5127-5138
DOI: 10.1021/acs.inorgchem.5b02737
16. O. M. Williams, J. Shi and M. J. Rose*. Photoelectrochemical Study of p-GaP(100)|ZnO|AuNP Devices: Strategies for Enhanced Electron Transfer and Aqueous Catalysis.
Chem. Commun. 2016, 9145-9148
DOI: 10.1039/C6CC00703A
15. D. R. Redman, H. J. Kim, K. J. Stevenson and M. J. Rose*. Photo-Assisted Electrodeposition of MoSx from Ionic Liquids on Organic-Functionalized Silicon Photoelectrodes for H2 Generation.
J. Mater. Chem. A. 2016, 4, 7027-7035
DOI: 10.1039/c5ta09684g
14. L. V. Taylor, U. H. Soto, V. M. Lynch and M. J. Rose*. Antimony-Supported Cu4I4 Cuboid with Short Cu-Cu Bonds: Premise for NIR Thermoluminescence.
Inorg. Chem. 2016, 55, 3206-3208
DOI: 10.1021/acs.inorgchem.5b02933
13. H. J. Kim, J. Seo and M. J. Rose*. H2 Photogeneration Using a Phosphonate-Anchored Ni-PNP Catalyst on a Band-Edge-Modified p-Si(111)|AZO Construct.
ACS Appl. Mater. Interfaces 2016, 8, 1061-1066
DOI: 10.1021/acsami.5b09902
12. G. Durgaprasad, Z.-L. Xie and M. J. Rose*. Iron Hydride Detection and Intramolecular Hydride Transfer in a Synthetic Model of Mono-Iron Hydrogenase with a CNS Chelate.
Inorg. Chem. 2016, 55, 386-389
DOI: 10.1021/acs.inorgchem.5b01733
11. T. Manes and M. J. Rose*. A Bis-pyridine Rhenium Carbonyl Derived from an Anthracene Scaffold: Redox Properties and its Electrocatalytic CO2→CO Reduction Activity.
Inorg. Chem. Commun. 2015, 61, 221-224
DOI: 10.1016/j.inoche.2015.10.012
10. F. Li, V. M. Basile and M. J. Rose*. Electron Transfer through Surface-Grown, Ferrocene-Capped Oligophenylene Molecular Wires (5-50 A) on n-Si(111) Photoelectrodes.
Langmuir 2015, 31, 7712-7716
DOI: 10.1021/acs.langmuir.5b02121
9. J. Seo, R. T. Pekarek and M. J. Rose*. Photoelectrochemical Operation of a Surface-Bound, Nickel-Phosphine H2 Evolution Catalyst on p-Si(111): A Molecular Semiconductor|Catalyst Construct.
Chem. Commun. 2015, 51, 13264-13267
DOI: 10.1039/c5cc02802g
8. H. J. Kim, K. L. Kearney. L. Le, R. T. Pekarek and M. J. Rose*. Platinum-Enhanced Electron Transfer through Ultra-Thin Film Aluminum Oxide (Al2O3) on Si(111) Photoelectrodes.
ACS Appl. Mat. Interfaces. 2015, 7, 8572-8584
DOI: 10.1021/acsami.5b00376
7. O. M. Williams, A. H. Cowley and M. J. Rose*. Structural and Electronic Characterization of Multi-Electron Reduced Naphthalene(BIAN) Cobaloximes.
Dalton Trans. 2015, 44, 13017-13029
DOI: 10.1039/C5DT00924C
6. K. A. Thomas Muthiah, G. Durgaprasad, Z.-L. Xie, O. M. Williams, C. Joseph, V. M. Lynch and M. J. Rose*. Mononuclear Iron(II) Dicarbonyls Derived from NNS Ligands: Structural Models Related to a Possible “Pre-Acyl” Active Site of Mono-Iron (Hmd) Hydrogenase.
Eur. J. Inorg. Chem. 2015, 1675-1692
DOI: 10.1002/ejic.201403013
5. J. Seo, H. J. Kim, R. T. Pekarek and M. J. Rose*. Hybrid Organic/Inorganic Band-Edge Modulation of p-Si(111) Photoelectrodes: Effects of R, Metal Oxide, and Pt on H2 Generation.
J. Am. Chem. Soc. 2015, 137, 3173-3176
DOI: 10.1021/ja5126287
4. F. Li, V. M. Basile, R. T. Pekarek and M. J. Rose*. Steric Spacing of Molecular Linkers on Si(111) Photoelectrodes.
ACS Appl. Mater. Interfaces 2014, 6, 20557-20568
DOI: 10.1021/am506244m
3. J. Seo, A. Ali and M. J. Rose*. Novel Ligand Architectures for Metalloenzyme Modeling: Anthracene-Based Ligands for Synthetic Modeling of Mono-[Fe] Hydrogenase.
Comments Inorg. Chem. 2014, 34, 103-114
DOI: 10.1080/02603594.2014.961062
2. S. E. A. Lumsden, G. Durgaprasad, K. A. Thomas Muthiah and M. J. Rose*. Tuning Coordination Modes of Pyridine/Thioether Schiff Base (NNS) Ligands to Mononuclear Manganese Carbonyls.
Dalton Trans. 2014, 43, 10725-10738
DOI: 10.1039/c4dt00600c
1. Y. I. Cho, D. M. Joseph and M. J. Rose*. ‘Criss-Crossed’ Dinucleating Behavior of an N4 Schiff Base Ligand: Formation of a mu-O2, mu-OH Dicobalt(III) Core via O2 Activation.
Inorg. Chem. 2013, 52, 13298-13300
DOI: 10.1021/ic402391f
MJR Postdoctoral Publications
6. J. R. McKone, S. Ardo, J. D. Blakemore, P. J. Bracher, J. L. Dempsey, T. V. Darnton, M. C. Hansen, W. H. Harman, M. J. Rose, M. G. Walter, S. Dasgupta, J. R. Winkler, and H. B. Gray. The Solar Army: A Case Study in Outreach Based on Solar Photoelectrochemistry.
Rev. Adv. Sci. Eng. 2014, 3, 288-303
DOI: http://dx.doi.org/10.1166/rase.2014.1076
5. L. E. O’Leary, M. J. Rose, T. Ding, E. Johansson, B. S. Brunschwig, N. S. Lewis, Nathan. Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces.
J. Am. Chem. Soc. 2013, 135, 10081
DOI: 10.1021/ja402495e
4. M. J. Rose, H. B. Gray and J. R. Winkler. Hydrogen Generation Catalyzed by Perfluorinated Diglyoxime-Iron Complexes at Low Overpotentials.
J. Am. Chem. Soc. 2012, 134, 8310
DOI: 10.1021/ja300534r
3. M. J. Rose, J. R. Winkler and H. B. Gray. Four-Iron Cluster and a Buckled Macrocycle Complex from Reduction of [(dmgBF2)Fe(L)2] (L=MeCN, tBuiNC).
Inorg. Chem. 2012, 51, 1980
DOI: 10.1021/ic202253v
2. M. J. Rose, D. E. Bellone and H. B. Gray. Spectroscopic and Magnetic Characterization of an Iodo Co(I) Tripodal Phosphine Complex.
Dalton Trans. 2012, 41, 11788
DOI: 10.1039/C2DT31229H
1. Q. Dong, M. J. Rose, W.-Y. Wong and H. B. Gray. Dual Coordination Modes of Ethylene Linked NP2 Ligands with Cobalt(II) and Nickel(II) Iodides.
Inorg. Chem. 2011, 50, 10213
DOI: 10.1021/ic201213c
MJR Graduate Publications
17. M. J. Rose, N. M. Betterley, A. Oliver, and P. K. Mascharak. Binding and Photorelease of Nitric Oxide (NO) to a Synthetic Model of Iron-Containing Nitrile Hydratase (Fe-NHase).
Inorg. Chem. 2010, 49, 1854-1864
DOI: 10.1021/ic902220a
16. M. J. Rose, A. K. Patra, M. M. Olmstead and P. K. Mascharak. Structural and Spectroscopic Evidence for Linkage Isomerism of Bound Nitrite in a {Fe-NO}6 Nitrosyl derived from a Tetradentate Dicarboxamide Ligand: More Parallels between Heme and Non-heme Systems.
Inorg. Chim. Acta 2010, 363, 2715
DOI: 10.1016/j.ica.2010.04.023
15. N. Fry, M. J. Rose, David L. Rogow, C. Nyitray, Manpreet Kaur and P. K. Mascharak. Ruthenium Nitrosyls Derived from Tetradentate Ligands containing Carboxamido-N and Phenolato-O Donors: Syntheses, Structures, Photolability and Time-Dependent Density Functional Studies.
Inorg. Chem. 2010, 49, 1487
DOI: 10.1021/ic9017129
14. M. J. Rose, N. M. Betterley, P. K. Mascharak. Thiolate S-Oxygenation Controls Nitric Oxide (NO) Photolability of a Synthetic Iron Nitrile Hydratase (Fe-NHase) Model Derived from Mixed Carboxamide/Thiolate Ligand.
J. Am. Chem. Soc. 2009, 131, 8340-8341
DOI: 10.1021/ja9004656
13. M. J. Rose, P. K. Mascharak. Photosensitization of Ruthenium Nitrosyls to Visible Light with an Isoelectronic Series of Heavy-Atom Chromophores: Experimental and DFT Studies on the Effects of O-, S- and Se-Substituted Coordinating Dyes.
Inorg. Chem. 2009, 48, 6904-6917
DOI: 10.1021/ic900899j
12. N. Fry, M. J. Rose, C. Nyitray, and P. K. Mascharak. Metal Nitrosyls with Phosphine Ligation: Unexpected Ligand Oxidation and Ring Nitration.
Inorg. Chem. 2008, 47, 11604-11610
DOI: 10.1021/ic801243a
11. M. J. Rose and P. K. Mascharak. A Photosensitive {Ru-NO}6 Nitrosyl Bearing Dansyl Chromophore: Novel NO Donor with a Fluorometric On/Off Switch.
Chem. Commun. 2008, 3933-3935
DOI: 10.1039/B805332D
10. M. J. Rose, N. Fry, R. Marlow, L. Hinck and P. K. Mascharak. Ruthenium Nitrosyls bearing Coordinated Fluorophores as NO Donors: a Novel Mode of Fluorometric Delivery of NO to Cells with Visible Light.
J. Am. Chem. Soc. 2008, 130, 8834-8846
DOI: 10.1021/ja801823f
9. M. J. Rose, P. K. Mascharak. Photoactive Ruthenium Nitrosyls: Effects of Light & Potential as Biological NO Donors.
Coord. Chem. Rev. 2008, 252, 2093-2114
DOI: 10.1016/j.ccr.2007.11.011
8. M. J. Rose and P. K. Mascharak. Fiat Lux: Selective Delivery of High Flux of Nitric Oxide (NO) to Biological Targets using Photosensitive Metal Nitrosyls.
Curr. Opin. Chem. Biol. 2008, 12, 238-244
DOI: 10.1016/j.cpba.2008.02.009
7. M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photosensitization via Dye Coordination: A New Strategy to Synthesize Metal Nitrosyls that Release NO under Visible Light.
J. Am. Chem. Soc. 2007,129, 5342-5343
DOI: 10.1021/ja070247x
6. M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photoactive Ruthenium Nitrosyls Derived from Quinoline- and Pyridine-based Ligands: Accelerated Photorelease of NO due to Quinoline Ligation.
Polyhedron 2007, 26, 4713-4718
DOI: 10.1016/j.poly.2007.03.010
5. M. J. Rose, A. K. Patra, E. A. Alcid, M. M. Olmstead and P. K. Mascharak. Carboxamido and Schiff Base Ruthenium Nitrosyls: Isoelectronic Complexes with Markedly Different Properties of Photolability and Reactivity.
Inorg. Chem. 2007, 46, 2328-2338
DOI: 10.1021/ic0620945
4. M. J. Rose,* I. Szundi,* I. Sen, A. A. Eroy-Reveles, P. K. Mascharak and Ó. Einarsdóttir. New Approach for Studying Fast Biological Reactions Involving Nitric Oxide: Generation of NO Using Photolabile Ruthenium and Manganese NO Donors.
Photochem. Photobiol. 2006, 82, 1377-1384
DOI: 10.1562/2006-07-25-RC-984
*3. D. C. Swinney, M. J. Rose, A. Y. Mak, I. Lee, L. Scarafia and Y. Xu. Bi-Substrate Kinetic Analysis of an E3–Ligase–Dependent Ubiquitylation Reaction.
Methods Enzymol. 2005, 399, 323-333
DOI: 10.1016/S0076-6879(05)99022-8
2. A. K. Patra, M. J. Rose, M. M. Olmstead and P. K. Mascharak. Reactions of Nitric Oxide with a Low-spin Fe(III) Center Ligated to a Tetradentate Di-carboxamide N4 Ligand: Parallels between Heme and Non-Heme Systems.
J. Am. Chem. Soc. 2004, 126, 4780-4781
DOI: 10.1021/ja040015n
1. A. K. Patra, M. J. Rose, K. A. Murphy, M. M. Olmstead and P. K. Mascharak. Photolabile Ruthenium Nitrosyls with Planar Di-carboxamide Tetradentate N4 Ligands: Effects of In-plane and Axial Ligand Strength on NO Release.
Inorg. Chem. 2004, 43, 4487-4495
DOI: 10.1021/ic040030t
MJR Industry Work
*2. M. J. Rose, I. Lee, T. R. Chapman and D. C. Swinney. Pharmacological Characterization of Clinical Anti-Cholinergic Drugs at M1–M5 Receptor Sub-types.
Mol. Biol. Cell. 2002, 443, 79A
*1. D. C. Swinney, M. J. Rose, I. Lee, A. Y. Mak. The Mono-ubiquitination of IkBa S32/36E in vitro Shows a Random Bi-Bi Kinetic Mechanism with Respect to IkBa-ee and E2UBCH7.
FASEB J. 2001, 15, A26
*Denotes publication or conference abstract from industry research