Rose Group Publications (MJR Independent Career)

27. S. Kerns, A.-C. Magtaan, P. Vong and M. J. Rose. Functional Hydride Transfer by a Thiolate-containing  Model of Mono-iron Hydrogenase featuring an Anthracene Scaffold. Angew. Chem. Int. Ed. 2018, In press. DOI: 10.1002/anie.201712948

26. T. A. Manes and M. J. Rose. Rigid scaffolds for the design of molecular catalysts and biomimetic active sites: A case study of anthracene-based ligands for modeling mono-iron hydrogenase (Hmd). Coord. Chem. Rev. 2017, 353, 295-308. DOI: 10.1016/j.ccr.2017.09.022

25. Z.-L. Xie, G. Durgaprasad and M. J. Rose. Substitution Reactions of Iron(II) Carbamoyl-Thioether Complexes Related to Mono-Iron Hydrogenase. Dalton Trans. 2017, 46, 10814. DOI: 10.1039/C7DT01696D

24. D. W. Redman, M. J. Rose and K. J. Stevenson. Electrodeposition of Amorphous Molybdenum Chalcogenides from Ionic Liquids and Their Activity for the Hydrogen Evolution Reaction. Langmuir 2017, 33, 9354-9360. DOI: 10.1021/acs.langmuir.7b00821

23. J. P. Shupp, A. R. Rose and M. J. Rose. Synthesis and Interconversions of Reduced, Alkali-Metal Supported Iron-Sulfur-Carbonyl Complexes. Dalton Trans. 2017, 46, 9163-9171. DOI: 10.1039/C7DT01506B

22. J. Seo, T. E. Sotman, E. R. Sullivan, B. D. Ellis, T. Phung and M. J. Rose. Structural and Electronic Modifications of Pyridones and Pyrones via Regioselective Bromination and Trifluoromethylation. Tetrahedron 2017, 73, 4519-4528. DOI: 10.1016/j.tet.2017.05.082

21. S. Kuppuswamy, J. Wofford, C. Joseph, Z.-L. Xie, A. K. Ali, V. M. Lynch, P. A. Lindahl, and M. J. Rose. Structures, Interconversions and Spectroscopy of Carbonyl Clusters with an Interstitial Carbide: Localized Iron Center Reduction via Cluster Oxidation. Inorg. Chem. 2017, 56, 5998-6012. DOI: 10.1021/acs.inorgchem.7b00741

20. J. Seo, T. A. Manes and M. J. Rose. Structural and Functional Synthetic Model of Mono-Iron Hydrogenase Featuring an Anthracene Scaffold. Nature Chem. 2017, 9, 552-557. DOI:10.1038/nchem.2707

19. H. J. Kim, K. L. Kearney, L. H. Le, Z. J. Haber, A. A. Rockett and M. J. Rose. Charge-Transfer through Ultrathin Film TiO2 on n-Si(111) Photoelectrodes: Experimental and Theoretical Investigation of Electric Field-Enhanced Transport with a Non-Aqueous Redox Couple. J. Phys. Chem. C 2016, 120, 25697-25708.  DOI: 10.1021/acs.jpcc.6b08096

18. Y. I. Cho, M. L. Ward and M. J. Rose. Substituent Effects of N4 Schiff Base Ligands on the Formation of Fluoride-Bridged Dicobalt(II) Complexes via B–F Abstraction: Structures and Magnetism. Dalton Trans. 2016, 45,13466-13476. DOI: 10.1039/C6DT02104B

17. T. A. Manes and M. J. Rose. Mono- and Di-nuclear Manganese Carbonyls Supported by 1,8-Disubstituted (L = Py, Ar-SMe, Ar-SH) Anthracene Ligand Scaffolds. Inorg. Chem. 2016, 55, 5127-5138. DOI: 10.1021/acs.inorgchem.5b02737

16. O. M. Williams, J. Shi and M. J. Rose. Photoelectrochemical Study of p-GaP(100)|ZnO|AuNP Devices: Strategies for Enhanced Electron Transfer and Aqueous Catalysis. Chem. Commun. 2016, 9145-9148. DOI: 10.1039/C6CC00703A

15. D. R. Redman, H. J. Kim, K. J. Stevenson and M. J. Rose. Photo-Assisted Electrodeposition of MoSx from Ionic Liquids on Organic-Functionalized Silicon Photoelectrodes for H2 Generation. J. Mater. Chem. A. 2016, 4, 7027-7035. DOI: 10.1039/c5ta09684g

14. L. V. Taylor, U. H. Soto, V. M. Lynch and M. J. Rose. Antimony-Supported Cu4I4 Cuboid with Short Cu-Cu Bonds: Premise for NIR Thermoluminescence. Inorg. Chem. 2016, 55, 3206-3208. DOI: 10.1021/acs.inorgchem.5b02933

13. H. J. Kim, J. Seo and M. J. Rose. H2 Photogeneration Using a Phosphonate-Anchored Ni-PNP Catalyst on a Band-Edge-Modified p-Si(111)|AZO Construct. ACS Appl. Mater. Interfaces, 2016, 8, 1061-1066. DOI: 10.1021/acsami.5b09902

12. T. Manes and M. J. Rose. A Bis-pyridine Rhenium Carbonyl Derived from an Anthracene Scaffold: Redox Properties and its Electrocatalytic CO2→CO Reduction Activity. Inorg. Chem. Commun 2015, 61, 221-224. DOI: 10.1016/j.inoche.2015.10.012

11. G. Durgaprasad, Z.-L. Xie and M. J. Rose. Iron Hydride Detection and Intramolecular Hydride Transfer in a Synthetic Model of Mono-Iron Hydrogenase with a CNS Chelate. Inorg. Chem. 2016, 55, 386-389. DOI: 10.1021/acs.inorgchem.5b01733

10. F. Li, V. M. Basile and M. J. Rose. Electron Transfer through Surface-Grown, Ferrocene-Capped Oligophenylene Molecular Wires (5-50 A) on n-Si(111) Photoelectrodes. Langmuir, 2015, 31, 7712-7716. DOI: 10.1021/acs.langmuir.5b02121

9. J. Seo, R. T. Pekarek and M. J. Rose. Photoelectrochemical Operation of a Surface-Bound, Nickel-Phosphine H2 Evolution Catalyst on p-Si(111): A Molecular Semiconductor|Catalyst Construct. Chem. Commun. 2015, 51, 13264-13267. DOI: 10.1039/c5cc02802g

8. H. J. Kim, K. L. Kearney. L. Le, R. T. Pekarek and M. J. Rose. Platinum-Enhanced Electron Transfer through Ultra-Thin Film Aluminum Oxide (Al2O3) on Si(111) Photoelectrodes. ACS Appl. Mat. Intfc. 2015, 7, 8572-8584. DOI: 10.1021/acsami.5b00376

7. O. M. Williams, A. H. Cowley and M. J. Rose. Structural and Electronic Characterization of Multi-Electron Reduced Naphthalene(BIAN) Cobaloximes. Dalton Trans. 2015, 44, 13017-13029. DOI: 10.1039/C5DT00924C

6. K. A. Thomas Muthiah, G. Durgaprasad, Z.-L. Xie, O. M. Williams, C. Joseph, V. M. Lynch and M. J. Rose. Mononuclear Iron(II) Dicarbonyls Derived from NNS Ligands: Structural Models Related to a Possible “Pre-Acyl” Active Site of Mono-Iron (Hmd) Hydrogenase. Eur. J. Inorg. Chem. 2015, 1675-1692. DOI: 10.1002/ejic.201403013

5. J. Seo, H. J. Kim, R. T. Pekarek and M. J. Rose. Hybrid Organic/Inorganic Band-Edge Modulation of p-Si(111) Photoelectrodes: Effects of R, Metal Oxide, and Pt on H2 Generation. J. Am. Chem. Soc. 2015, 137, 3173-3176. DOI: 10.1021/ja5126287

4. F. Li, V. M. Basile, R. T. Pekarek and M. J. Rose. Steric Spacing of Molecular Linkers on Si(111) Photoelectrodes. ACS Appl. Mater. Interfaces, 2014, 6, 20557-20568. DOI: 10.1021/am506244m

3. J. Seo, A. Ali and M. J. Rose. Novel Ligand Architectures for Metalloenzyme Modeling: Anthracene-Based Ligands for Synthetic Modeling of Mono-[Fe] Hydrogenase. Comments Inorg. Chem. 2014, 34, 103-114. DOI: 10.1080/02603594.2014.961062

2. S. E. A. Lumsden, G. Durgaprasad, K. A. Thomas Muthiah and M. J. Rose. Tuning Coordination Modes of Pyridine/Thioether Schiff Base (NNS) Ligands to Mononuclear Manganese Carbonyls. Dalton Trans. 43, 2014, 10725-10738. DOI: 10.1039/c4dt00600c

1. Y. I. Cho, D. M. Joseph, M. J. Rose. ‘Criss-Crossed’ Dinucleating Behavior of an N4 Schiff Base Ligand: Formation of a mu-O2, mu-OH Dicobalt(III) Core via O2 Activation. Inorg. Chem. 2013, 52, 13298. DOI: 10.1021/ic402391f

MJR Postdoctoral Publications

6. J. R. McKone, S. Ardo, J. D. Blakemore, P. J. Bracher, J. L. Dempsey, T. V. Darnton, M. C. Hansen, W. H. Harman, M. J. Rose, M. G. Walter, S. Dasgupta, J. R. Winkler, and H. B. Gray. The Solar Army: A Case Study in Outreach Based on Solar Photoelectrochemistry. Rev. Adv. Sci. Eng. 2014, 3, 288-303. DOI:

5. L. E. O’Leary, M. J. Rose, T. Ding, E. Johansson, B. S. Brunschwig, N. S. Lewis, Nathan. Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces. J. Am. Chem. Soc. 2013, 135, 10081. DOI: 10.1021/ja402495e

4. M. J. Rose, H. B. Gray and J. R. Winkler. Hydrogen Generation Catalyzed by Perfluorinated Diglyoxime-Iron Complexes at Low Overpotentials. J. Am. Chem. Soc. 2012, 134, 8310. DOI: 10.1021/ja300534r

3. M. J. Rose, J. R. Winkler and H. B. Gray. Four-Iron Cluster and a Buckled Macrocycle Complex from Reduction of [(dmgBF2)Fe(L)2] (L=MeCN, tBuiNC). Inorg. Chem. 2012, 51, 1980. DOI: 10.1021/ic202253v

2. M. J. Rose, D. E. Bellone and H. B. Gray. Spectroscopic and Magnetic Characterization of an Iodo Co(I) Tripodal Phosphine Complex. Dalton Trans. 2012, 41, 11788. DOI: 10.1039/C2DT31229H

1. Q. Dong, M. J. Rose, W.-Y. Wong and H. B. Gray. Dual Coordination Modes of Ethylene Linked NP2 Ligands with Cobalt(II) and Nickel(II) Iodides. Inorg. Chem. 2011, 50, 10213. DOI: 10.1021/ic201213c

MJR Graduate Publications

17. M. J. Rose, N. M. Betterley, A. Oliver, and P. K. Mascharak. Binding and Photorelease of Nitric Oxide (NO) to a Synthetic Model of Iron-Containing Nitrile Hydratase (Fe-NHase). Inorg. Chem. 2010, 49, 1854-1864. DOI: 10.1021/ic902220a

16. M. J. Rose, A. K. Patra, M. M. Olmstead and P. K. Mascharak. Structural and Spectroscopic Evidence for Linkage Isomerism of Bound Nitrite in a {Fe-NO}6 Nitrosyl derived from a Tetradentate Dicarboxamide Ligand: More Parallels between Heme and Non-heme Systems. Inorg. Chim. Acta 2010, 363, 2715. Link

15. N. Fry, M. J. Rose, David L. Rogow, C. Nyitray, Manpreet Kaur and P. K. Mascharak. Ruthenium Nitrosyls Derived from Tetradentate Ligands containing Carboxamido-N and Phenolato-O Donors: Syntheses, Structures, Photolability and Time-Dependent Density Functional Studies. Inorg. Chem. 2010, 49, 1487. DOI: 10.1021/ic9017129

14. M. J. Rose, N. M. Betterley, P. K. Mascharak. Thiolate S-Oxygenation Controls Nitric Oxide (NO) Photolability of a Synthetic Iron Nitrile Hydratase (Fe-NHase) Model Derived from Mixed Carboxamide/Thiolate Ligand. J. Am. Chem. Soc. 2009, 131, 8340-8341. DOI: 10.1021/ja9004656

13. M. J. Rose, P. K. Mascharak. Photosensitization of Ruthenium Nitrosyls to Visible Light with an Isoelectronic Series of Heavy-Atom Chromophores: Experimental and DFT Studies on the Effects of O-, S- and Se-Substituted Coordinating Dyes. Inorg. Chem. 2009, 48, 6904-6917. DOI: 10.1021/ic900899j

12. N. Fry, M. J. Rose, C. Nyitray, and P. K. Mascharak. Metal Nitrosyls with Phosphine Ligation: Unexpected Ligand Oxidation and Ring Nitration. Inorg. Chem. 2008, 47, 11604-11610. DOI: 10.1021/ic801243a

11. M. J. Rose and P. K. Mascharak. A Photosensitive {Ru-NO}6 Nitrosyl Bearing Dansyl Chromophore: Novel NO Donor with a Fluorometric On/Off Switch. Chem. Commun. 2008, 3933-3935. DOI: 10.1039/B805332D

10. M. J. Rose, N. Fry, R. Marlow, L. Hinck and P. K. Mascharak. Ruthenium Nitrosyls bearing Coordinated Fluorophores as NO Donors: a Novel Mode of Fluorometric Delivery of NO to Cells with Visible Light. J. Am. Chem. Soc. 2008, 130, 8834-8846. DOI: 10.1021/ja801823f

9. M. J. Rose, P. K. Mascharak. Photoactive Ruthenium Nitrosyls: Effects of Light & Potential as Biological NO Donors. Coord. Chem. Rev. 2008, 252, 2093-2114. Link

8. M. J. Rose and P. K. Mascharak. Fiat Lux: Selective Delivery of High Flux of Nitric Oxide (NO) to Biological Targets using Photosensitive Metal Nitrosyls. Curr. Opin. Chem. Biol. 2008, 12, 238-244. Link

7. M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photosensitization via Dye Coordination: A New Strategy to Synthesize Metal Nitrosyls that Release NO under Visible Light. J. Am. Chem. Soc. 2007,129, 5342-5343. DOI: 10.1021/ja070247x

6. M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photoactive Ruthenium Nitrosyls Derived from Quinoline- and Pyridine-based Ligands: Accelerated Photorelease of NO due to Quinoline Ligation. Polyhedron 2007, 26, 4713-4718. Link

5. M. J. Rose, A. K. Patra, E. A. Alcid, M. M. Olmstead and P. K. Mascharak. Carboxamido and Schiff Base Ruthenium Nitrosyls: Isoelectronic Complexes with Markedly Different Properties of Photolability and Reactivity. Inorg. Chem. 2007, 46, 2328-2338. DOI: 10.1021/ic0620945

4. M. J. Rose,* I. Szundi,* I. Sen, A. A. Eroy-Reveles, P. K. Mascharak and Ó. Einarsdóttir. New Approach for Studying Fast Biological Reactions Involving Nitric Oxide: Generation of NO Using Photolabile Ruthenium and Manganese NO Donors. Photochem. Photobiol. 2006, 82, 1377-1384  (*equal authorship). DOI: 10.1562/2006-07-25-RC-984

*3. D. C. Swinney, M. J. Rose, A. Y. Mak, I. Lee, L. Scarafia and Y. Xu. Bi-Substrate Kinetic Analysis of an E3–Ligase–Dependent Ubiquitylation Reaction. Methods Enzymol. 2005, 399, 323-333. Link

2. A. K. Patra, M. J. Rose, M. M. Olmstead and P. K. Mascharak. Reactions of Nitric Oxide with a Low-spin Fe(III) Center Ligated to a Tetradentate Di-carboxamide N4 Ligand: Parallels between Heme and Non-Heme Systems. J. Am. Chem. Soc. 2004, 126, 4780-4781. DOI: 10.1021/ja040015n

1. A. K. Patra, M. J. Rose, K. A. Murphy, M. M. Olmstead and P. K. Mascharak. Photolabile Ruthenium Nitrosyls with Planar Di-carboxamide Tetradentate N4 Ligands: Effects of In-plane and Axial Ligand Strength on NO Release. Inorg. Chem. 2004, 43, 4487-4495. DOI: 10.1021/ic040030t

MJR Industry Work

*2. M. J. Rose, I. Lee, T. R. Chapman and D. C. Swinney. Pharmacological Characterization of Clinical Anti-Cholinergic Drugs at M1–M5 Receptor Sub-types. Mol. Biol. Cell. 2002, 443, 79A

*1. D. C. Swinney, M. J. Rose, I. Lee, A. Y. Mak. The Mono-ubiquitination of IkBa S32/36E in vitro Shows a Random Bi-Bi Kinetic Mechanism with Respect to IkBa-ee and E2UBCH7. FASEB J. 2001, 15, A26

    *Denotes publication or conference abstract from industry research